What Is A Logo - 1474 Words

What is a logo? In today’s world, it is very important for organizations to protect their intellectual property, otherwise known as creations or inventions, literary or artistic works, symbols and designs, and names and images usually for the purpose of commerce. Intellectual property (IP) is protected in law by trademarks, copyrights, trade secrets, and patents that provide recognition of their security. A logo is a symbol, design, or graphic that is affiliated with a brand, company, or organization to identify a source of goods. Copyright vs. Trademark Logos belong in their own category of IP, where there is a grey area of what means of protection is necessary, somewhere between copyright and trademark. Businesses are known to use both to protect such logos. Companies that provide services for logos, branding, and merchandising from a third party standard often feel the ramifications of misusing their customer’s logos for their own marketing purposes. Copyright and trademark infringement are among the most common types of marketing misuse. There is often confusion between using protections with copyrights versus trademarks. A copyright protects an original work of authorship fixed in a tangible medium of expression. However, a trademark protects sources, including words, symbols, smells, pictures, and sounds, that are used to identify the source of goods and distinguish them from goods sold by others (Harazin 2012). Generally speaking, when most people think ofShow MoreRelatedWhat Is The Logo Of Youtu be748 Words   |  3 Pageschanges to the site’s layout, settings, and format over the years, however, the looks of the sites homepage and the logo always remained familiar. In last 12 years, YouTube’s logo has become immensely popular on the web. The sites logo is one of the most widely recognized logos among the web users. The logo can be divided into two features, You and Tube. The first feature of the logo is the word You written in black. The second feature is the word Tube bounded by a red rounded rectangle separatingRead MoreWhat Is The Theme Of Pathos And Logos In The Odyssey929 Words   |  4 PagesAfter returning from war, veterans often face many hardships. This theme is demonstrated through pathos and logos in both â€Å"The Odyssey† by Homer and â€Å"Back from War but Not Really Home† by Caroline Alexander. These texts use these rhetorical devices to prove that a soldier’s struggle does not stop when he leaves the battlefield. By do ing so, they open the eyes of the reader to the injustice they face. In both articles, pathos, or emotional appeal, is used to show the awkwardness between survivorsRead MoreLogo Research Paper1300 Words   |  6 Pages{Why You Should Choose Online Logo Designers|Benefits of Selecting Online Logo Designers|Reasons Why Online Logo Designers are Great Choices} {Logos are a critical part of a businesss image because they represent a companys ideologies in a symbol.|Logos are significant to a companys persona and they represent a companys story in a single emblem.|Logos are important to a businesss personality and they signify a corporations ideas in a simple image.} {The symbol needs to be accurate about theirRead MoreLogo Designs: Faulty When Ugly Essay1112 Words   |  5 Pagesbecame a necessity within that time. Today, it is more commonly known as --a logo design. Majority of businesses today find it reasonable to represent themselves with a logo, that in which speaks for their company or foundation as a whole in its entirety. Its use has gained importance within social media, substantially. The most important aspect of a company’s platform should be the concern within the creation of the logo design because it is the standing point of a first impression, symbolizes identityRead MoreCreating A Good And Memorable Logo1299 Words à ‚  |  6 PagesJust assuming, when most people think of logo design, the image probably goes something like this. A scruffy man, with a graphic T-shirt is sitting in front of a Macintosh computer monitor, with Photoshop open and putting the final touches on the changes of a logo he found in Google images. This scenario, however plausible sounding, is usually incorrect. There are many different and complicated steps that go into creating a logo, and even more steps that go into making a good one. Drafts upon draftsRead MoreEssay On Logos1082 Words   |  5 Pagesedge to help your IT company capture potential customers attention. A good logo helps you do that.   In fact, some major tech companies are as easily recognized by their logos as by their names.   Technology has advanced enough that you can even take on the whole process yourself with inexpensive or free logo design software. Even better, these days you can create 3D logos that stand out even more. Of course, a good 3d logo design doesnt appear out of nowhere. You need to build it up step by stepRead MoreThe North Face1305 Words   |  6 Pageswell. The logo plays a huge role in the spread of a business. All it takes is a glance at someone’s jacket for a new customer to discover the iconic brand. The North Face logo is brilliant in the fact that it is simple yet unmistakable. At first glance, one might consider The North Face logo is too simple, but in reality that is the beauty of it. This simple logo design helps a viewer stray away from any unintended conclusions by random bystanders. It is evident the designer of this logo used manyRead MoreLogos Ethos Pathos1236 Words   |  5 Pagesï » ¿ In Neil Postman’s novel, Amusing Ourselves to Death, he argues that rationality in America has become dictated by television. Through the use of ethos, pathos, and logos, Postman demonstrates that his claim is valid and reliable. These are three forms of persuasion that are used to influence others to agree with a particular point of view. Ethos, or ethical appeal, is used to build an author’s image. Ethos establishes a sense of credibility and good character for the author (Henning). Pathos, orRead MoreInquiring And Analyzing The Problem984 Words   |  4 PagesInquiring and Analyzing What is the problem? 1.My Logo can’t be so big enough, I need to think some other patterns. 2.I don’t know how to draw it on computer. 3.I need more ideas. 4.I need to sure my personality is. 5.I don’t know how to design a thing. I never done it. Who is it a problem for? Myself. Where is the problem occurring? At the computer. What is the cause of the problem? The problem is I can’t use computer very well.Like how to find some similar to my logo’s picture, and how to use theRead MoreGraphic Design And Designing A Design998 Words   |  4 PagesGraphic design and experience are needed to design logos, and other marketing material for the client. Those skills are learned in educational programs. The fact is that the new or inexperienced graphic designer requires some helpful advice on the important questions to ask a client before designing a logo for their company. Otherwise, the logo design project might hit a few stumbling blocks. The questions here are a good starting point for a logo design. However, they are also standard question to

Rudolf diesel Free Essays

Rudolf Diesel was born on March 18, 1858 in Paris France the second of three children of Elise and Theodor diesel. Diesel spent is early childhood in France but because of the Franco-Prussian war in 1870 his family was forced to leave and moved to London. At 12 years old his parents sent him to live with his aunt and uncle because they wanted him to attend royal country trade school where his uncle was a math teacher and to become fluent in German. We will write a custom essay sample on Rudolf diesel or any similar topic only for you Order Now At age 14 he wrote a letter to his parents saying how he wanted to be an engineer after finishing his education at top f his class, and then he enrolled at the new industrial school of Augsburg. Two years later he received a merit scholarship to attend the Royal Bavarian Polytechnic of Munich which he accepted instead of listening to his parents and starting work. Diesel could not graduate in July 1879 because he fell ill to typhoid (a bacterial disease resulting from ingestion of food or water exposed to feces). While he was waiting to take his exam he got engineering experience at sluzer bros machine works. After graduating in 1880 diesel went to work for his college professor Carl Von Linde o develop a refrigeration and ice factory, and became the director of the plant one year later. In 1890 he moved to Berlin where he started working toward better fuel economy for steam engines, he tried using ammonia vapor to gain his desired fuel economy but the engine blew up during testing. Later he tried to increase fuel economy by using the Carnot cycle which led him to his own theory of compression ignition engines, in these engines the fuel was not put into the cylinder until the end of the compression stroke and the fuel was ignited by the high temperatures from ompression. He obtained multiple patents for his design in the United States and Europe. After boarding a boat in 1913 to attend a meeting he was missing when the boat docked. A couple days later they found his body in the ocean but let the body back to sea after getting his id card and other things he was carrying. I think he was murdered because Hubert akroyd Stuart had put out a patent a couple years before diesel for a compression ignition engine but was told that diesels was slightly different so it was 0k. This is a clear motive for revenge!! How to cite Rudolf diesel, Papers

System Acquisition and Implementation Management †Free Samples

Question: Discuss about the System Acquisition and Implementation Management. Answer: Introduction: I think that a formal selection process is necessary for the organization to build their team members. I think that the use of the formal selection process in the company helps in outlining the specific requirements in the work environment and evaluating the work assessment of the company to meet the requirements. According to me, a proper selection of team leader helps in maintaining the team members in proper manner that helps in development of the company in the market. I think use of the SMART criteria during the selection process helps in creating an efficient team for development of company in the market (Chelladurai and Kerwin 2017). I think company might use informal selection process for having large candidates for recruitment (Wilton 2016). The informal process is used for selecting a large number of candidates over the internet using social network and other media sources. I think that using the wrong system for identifying requirements is a major issue in the company. The time required for selection process and identifying requirement is another issue for the company. Companies used to take long hours for identifying requirement during the selection process that creates less opportunity for the selection process (Sparrow, Brewster and Chung 2016). I think that prioritization is a technique by which the company can bound time limits process and prioritize them accordingly (Antwi et al. 2016). This might help in minimizing the time and creating more opportunities for the company to utilize selection process. Prioritization helps in maintaining a proper schedule for every stages of the selection process. According to me, selection of correct vendors is a major challenge for the company to identify products. The products provided by the vendor have to be of good quality that increases the customer satisfaction who the company in the market. The satisfaction of the customer is another issue for the company. I think that selection of correct vendor might help in selecting good vendor for providing products. I think company might use searches over internet that helps in finding proper vendors for the company in the market (Markoulli et al. 2017). According to me, initiating conferences and expos in the market helps in identifying proper vendors from the market (Brewster and Hegewisch 2017). References Chelladurai, P. and Kerwin, S., 2017.Human resource management in sport and recreation. Human Kinetics. Wilton, N., 2016.An introduction to human resource management. Sage. Sparrow, P., Brewster, C. and Chung, C., 2016.Globalizing human resource management. Routledge. Antwi, J.O., Opoku, A.C., Seth, A. and Margaret, O., 2016. Assessing the human resource management practices of public banks from employees perspective: case study of selected branches of Ghana commercial bank, Kumasi.Global Journal of Human Resource Management,4(1), pp.13-30. Brewster, C. and Hegewisch, A. eds., 2017.Policy and Practice in European Human Resource Management: The Price Waterhouse Cranfield Survey. Taylor Francis. Markoulli, M., Lee, C.I., Byington, E. and Felps, W.A., 2017. Mapping Human Resource Management: Reviewing the field and charting future directions.Human Resource Management Review,27(3), pp.367-396.

Religion Effect On Politics Essays - IslamicJewish Relations

Religion Effect On Politics The belief systems of the modern world have helped determine the policies and politics of nations around the world. For centuries before, and almost definitely for decades after now, there will be disputed between people and countries on account of their faith. Religions have started wars, ended them, impacted, and persuaded people. Needless to say, beliefs are very influential on the world today. People of different faiths don't only fight over their basic beliefs and land but they end conflicts. Making amends between religious groups greatly helps relieve the constant strain of division that we are all too aware of these days. The Lutheran religion began 482 years ago when monk, Martin Luther, attacked the practices of the Catholic Church. These who followed his ideas eventually into what we call Lutherans today. For those 482 years, Lutherans and Catholics have stayed divided on uneasy terms. Now the leaders of the modern Lutheran and Catholic churches both signed a document that laid to rest those many years of differences under the explanation that it was all a misunderstanding. Sometimes different faiths just don't seem like they want to even try to compromise on a conflict. The Jordanian Muslims and the Israeli Jews fighting over which side of the Jordan River Jesus was baptized on is a perfect example of this. The Muslims have invested over one million dollars t fix up the site. The site will bring in expectantly millions of tourists and with them billions of dollars that will be spent locally to boost the economy. Looking past the irony of the Jews and Muslims disputing over a Christian site, the focal point of the quarreling is that such a site will bring. The Pope and Prince Charles have already scheduled a visit, but as of now, no resolve has come about. These days it's not always conflicts between two specific regions, but between regions occupied by faiths who disagree on certain topics. The two groups being the Israelis and the Palestinians, and the compromise on the rift in the settler movement conflict arising in those countries. To the Jews the West Bank is part of the greater Land of Israel, given by God to the Jews. To cement their control over the land, the Jews built forty-two hilltop encampments on the West Bank. They did this to prevent it from becoming a Palestinian state. The Palestinian government claimed that some of the outposts didn't have the necessary building papers and twelve of those sites were dismantled. This disagreement is, for the time being, settled peacefully despite the denounced accord from the Palestinians. In the future more outposts are likely to be taken down. Whatever the rhyme or reason, religions and belief systems have tremendous effects on the way things work in this world. Hopefully nations are learning from their past mistakes what not to do if such an occasion arise again. Whether the Lutherans and Catholics are putting years of disagreement behind them, the Jews and Muslims are settling their dispute, or Jewish outposts are being taken down, we are moving forward into a new and brighter future, and gaining information as we go along. Maybe in the future, more of the religious spats will be settled as the Lutheran/Catholic dispute was...peacefully.

Disappointed + Preposition

Disappointed + Preposition Disappointed + Preposition Disappointed + Preposition By Maeve Maddox A reader asks: Could you write about which preposition should be used after disappointed (e.g., in, at, with, by)? Please explain the instances to use them correctly. I don’t think it’s possible to lay down a hard and fast rule about which preposition should follow disappointed, but I’ve gathered some headlines and quotations from the Web that illustrate what seems to me to be the most common usage. His military dad was disappointed in him. My parents are disappointed in me. Disappointment is an emotion. The preposition that follows disappointed hints at the intensity of the emotion involved. â€Å"Disappointed in† suggests that a betrayal has taken place. The source of the disappointment is usually a loved and trusted person whose actions are seen by another as a betrayal. The trusted person’s very character is in question. This kind of disappointment shakes a relationship. In is also used when trust has been placed in an entity or institution from which something else was expected: New Hope parents, students disappointed in courts decision Drivers in Liberia are expressing frustration and disappointment in the Federation of Road Transport Union (FRTUL) for its alleged failure to meet their needs. â€Å"Disappointed by† lacks the sense of betrayal conveyed by â€Å"disappointed in†; with by the emotion seems to be more one of surprise: Kim Simplis Barrow says she’s disappointed by church’s position â€Å"Disappointed with† seems to have the broadest application. We’re disappointed with products or with how things are done: †I am deeply disappointed with how WorkSafe conducted this investigation,† Clark told reporters. iPhone users are disappointed with the iOS 7.1 software update thats draining their batteries Julien Disappointed With Bruins’ Effort In  Winnipeg Chase disappointed with outcome of 2014 Legislative sessions Preposition use is changing rapidly. For example, nonstandard â€Å"excited for† is challenging standard â€Å"excited about† in the speech of younger speakers. If the established uses of â€Å"disappointed in† and â€Å"disappointed by† are displaced, it will be by â€Å"disappointed with,† as in this comment by Drake Bennett: Being disappointed with a person feels different from being disappointed with an outcome, and demands a different response. Want to improve your English in five minutes a day? Get a subscription and start receiving our writing tips and exercises daily! Keep learning! Browse the Expressions category, check our popular posts, or choose a related post below:50 Handy Expressions About Hands10 Colloquial Terms and Their Meanings45 Idioms About the Number One

Structure of a Descriptive Essay

Structure of a Descriptive Essay The descriptive essay can be arranged in one of many organization patterns, and you will soon find that one style is best for your particular topic. Some effective organization patterns for a descriptive essay are spatial, which is best used when you are describing a location; chronological organization, which is best used when you are describing an event; and functional organization, which is best used when you are describing how a device or process works. Start with a Mind Dump Before you can begin writing your essay or deciding upon an organizational pattern, you should put everything you know about your subject on a piece of paper in a mind dump. In this first stage of information gathering, you should not worry about organizing your information. To start out, simply write down every item, characteristic, or feature that you can think of, allowing your thoughts to flow onto the paper. Note: A giant sticky note is a fun tool for mind dumping. Once your paper is filled with bits of information, you can use a simple numbering system to begin identifying topics and subtopics. Simply look over your items and â€Å"clump† them together in logical groups. Your groups will become major topics that you address in body paragraphs. Come Up with an Overall Impression The next step is to read over your information to come up with one major impression that you get from it all. Ponder the information for a few moments and see if you can boil it all down to one thought. Sound difficult? This list below shows three imaginary topics (in bold) followed by examples of a few thoughts that might be generated about each topic. You will see that the thoughts lead to an overall impression (in italics). 1. Your City Zoo - The animals were arranged by continents. Each area featured interesting plants and flowers from the continents. There were beautiful murals painted everywhere. Impression: the visual elements make this a more interesting zoo. Structure: Since a zoo is a place, the best structure for the city zoo essay is likely to be spatial. As a writer, you would begin with an introductory paragraph that ends with a thesis statement based on your impression. A sample thesis state would be While the animals were fascinating, the visual elements made this zoo most interesting. You could write your essay as a walking tour, visiting (describing) one area at a time.Each area would be described in your body paragraphs.You would use descriptive language to convey the striking visual elements of each area. 2. A Birthday Party - The birthday boy cried when we sang to him. He was too young to know what was happening. The cake was too sweet. The sun was hot. Impression: this party was a disaster! Structure: Since this is an event in time, the best structure would likely be chronological. Your introductory paragraph would build up to the conclusion (your impression) that this party was not a success!Each disastrous event would be described in individual body paragraphs. 3. Making a Cake from Scratch - I learned what sifting was, and it was messy. Creaming butter and sugar takes time. It’s hard to pick slippery egg shell bits out of flour. We really take box mixes for granted! Structure: The best structure would be functional. You would build up to the (surprising) complexity of making a cake from scratch.Body paragraphs would address the difficulty you encountered at each turn. End with a Conclusion Every essay requires a good conclusion to tie things up and make a tidy and complete package. In your concluding paragraph for a descriptive essay, you should summarize your main points and explain your overall impression or thesis in new words.

Wk 3 disc(6100) Essay Example | Topics and Well Written Essays - 500 words

Wk 3 disc(6100) - Essay Example Because of this circumstances and impending threat, Patricia is experiencing anxiety and very nervous when she consulted Lisette. Moreover, she has already lost 15 pounds. In counseling, the one of the counselor’s role is to help the clients create their own road maps that would help them resolve their problem on their own. It is also a practice that counselor’s must not let their clients depend on them emotionally so they can become independent and realize that they make their own choices. In this case, this has not been observed since Shaun allowed himself to have an intimate affair with the counselee. In section 2.5 of the 2005 ACA Code of Ethics, counselors are prohibited from engaging in sexual or intimate affairs with their clients. Doing so means abuse of power since the counselor takes advantage of the vulnerability of the client. Koocher and Keith-Spiegel (1998) asserted that confidentiality is considered as â€Å"a cornerstone of the helping relationship†. Moreover, the element of trust has been betrayed which is the keystone in counseling. Shaun has gone beyond his limits and showed subjectivity by even threatening Patr icia to stop assisting her. Fisher ( 2008 ) argued that the counselor must be very aware that the â€Å"primary obligation† is again the protection of information , not just the protection of rights (Ethical Standard 4.01, Maintaining Confidentiality). Therefore, Shaun cannot disclose any information to anyone especially to Patricia’s live-in boyfriend. If he does, then he is liable for violating the Code of ACA. Lisette then must act immediately to protect the counselee from harm by requesting a transfer of the counselee to another counselor ( in this case, Lisette). Indeed, the situation has become complicated since Lisette has to deal with Shaun and at the same time, earning Patricia’s

Pulmonary Hypertension Essay Example | Topics and Well Written Essays - 5000 words

Pulmonary Hypertension - Essay Example Genetic factors may account for mutations in the blood vessels which may manifest in the increased prevalence of smooth muscle cells and fibroblasts in the walls of the blood vessels (Ali, Summer, and Levitzky, 2005). Pulmonary hypertension may also be caused by congenital heart defects like atrial septal defect, ventricular septal defect, patent ductus arteriosus, and congenital heart problems which have left to right shunts (Ali, Summer & Levitzky, 2005). In instances when the pulmonary hypertension would worsen, the right-side pressure may overwhelm systemic pressure and â€Å"poorly oxygenated mixed venous blood bypasses the lungs and enters the systemic circulation, causing severe shunt-related hypoxemia† (Ali, Summer & Levitzky, p.129, 2005). Non-specific symptoms like dyspnea on exertion, fatigue, angina pectoris, and syncope (Ali, Summer & Levitzky, 2005). These are however symptoms which also apply to other cardiopulmonary disorders like ischemic and valvular heart disorder. Hoarseness is a symptom more specific to pulmonary hypertension because it is caused by compression of the recurrent laryngeal nerve due to the enlarged main pulmonary artery (Ali, Summer & Levitzky, 2005). In cases of cardiac overload, sodium and water retention increases under the influence of the aldosterone hormone. Sodium and water retention consequently manifests as volume overload causing distended neck veins (jugular vein distention), ascites, and leg edema. Other symptoms may include tachypnea, dizziness, apprehension, fear, persistent hypoxemia, excessive fatigue, and cyanosis (Canobbio, 2006). Dizziness, fatigue and syncope are largely due to insufficient cardiac output (Newman, 2008). Initial diagnostic tests may include chest x-ray, spirometry, ECG, and echocardiography, and CBC following a complaint of significant exertional dyspnea in patients who seem relatively

Vietnam Currency Protectionism Essay Example for Free

Vietnam Currency Protectionism Essay Vietnams decision to devalue its currency by 5 per cent last week to protect itself from undervaluation of the Chinese renminbi, and the worried response from Thailand and other Asian countries, suggests the move towards global trade conflict may already be unstoppable. As one group of countries seeks to gain or maintain trade advantage by manipulating their currencies, the historical precedent suggests that countries that are not able to devalue will respond with trade protection, especially tariffs and other barriers, and global trade will suffer. In the 1930s many, but not all, major economies imposed draconian constraints on trade which sharply contracted international commerce and almost certainly slowed the global recovery. It was widely understood then that the collapse in international trade would only worsen the crisis, and yet countries, seeking to protect their own positions, collectively engaged in behaviour that left them worse off. American economists Barry Eichengreen and Douglas Irwin recently published a paper examining the roots of the post-1930 surge in protection. They argue that during the 1920s and shortly after the onset of the 1929 crisis, several countries abandoned the gold standard and engaged in beggar-thy-neighbour competitive devaluations. These countries subsequently experienced rapid improvements in their trade balances and suffered much less from the ravages of the global contraction of the 1930s. But others, most obviously the US and European gold bloc countries, were sharply constrained in their ability to adjust their currencies. These countries suffered much of the brunt of the adjustment as imports became more competitive against their domestic industries, especially in relation to countries that were less constrained. These were also the countries that were most likely to resort to what the authors call the second-best adjustment mechanisms tariffs, import quotas, exchange controls, and so on. The exchange rate regime and economic policies associated with it were key determinants of trade policies of the early 1930s, they wrote. Countries that remained on the gold standard, keeping their currencies fixed against gold, were more likely to restrict foreign trade. With other countries devaluing and gaining competitiveness at their expense, they adopted such policies to strengthen the balance of payments and fend off gold losses. That should not surprise us. In a world of contracting global demand policymakers were concerned not just with measures to boost domestic demand but also with measures that allowed them to acquire a greater share of foreign net demand. The easiest way to do this was by devaluation. But countries that were unable to realign their currencies remained under pressure to find alternative ways of helping their domestic industries. They resorted to tariffs and import quotas. The same thing may be happening again. Of course no currency is any longer tied to gold, so there is no country whose ability to devalue, as in the 1930s, is limited by a commitment to maintain gold parity. But there are countries whose abilities to manage their currencies are nonetheless severely constrained. The US dollar, for example, is widely believed to be overvalued, especially in relation to the currencies of Asian nations. Because of massive intervention by Asian central banks, however, it is proving almost impossible for the dollar to adjust sufficiently, except against floating currencies such as the euro. This creates a similar problem for Europe. Although few analysts believe the euro to be undervalued against the dollar indeed, most believe it is more likely to be overvalued it is nonetheless forced to bear the brunt of US dollar adjustment by further appreciation. This means that both the US and eurozone countries suffer from currency intervention and competitive devaluations elsewhere, with little room to adjust. What can the US and Europe do? If Messrs Eichengreen and Irwin are right, they are likely to resort to the same second-best options available to them as countries locked into overvalued gold exchange rates in the 1930s. They will raise tariffs or otherwise intervene directly in trade, and it is pretty clear already that as US and European anger over currency misalignment grows, the recourse to protectionism is also growing. Nearly everyone agrees that a world that retreats into direct and indirect forms of trade protection is a world that is worse off and likely to recover more slowly from the global crisis. But the fact that everyone seems to agree on this point should not allay our worries. In the 1930s, it was also well understood that the crisis would be exacerbated by plunging international trade. This did not stop a descent into protectionism which put the Great into the Great Depression. Once again it seems we are going to make the same mistake. Countries that can expand their share of global demand by competitive devaluations are seeking to do so. Countries that cannot will almost certainly consider more direct forms of intervention. We should worry. Without serious global co-ordination, in which the US and Europe forswear protectionism in exchange for significant appreciation of undervalued currencies, rising tariffs appear inevitable.

Comparative Fascism in Europe :: Essays Papers

Comparative Fascism in Europe Is it â€Å"easier† to write a fascist credo than an anti-fascist credo? Why or why not? Fascism was an enforced State while antifascism was a chosen opposition Defining a fascist credo is difficult because the fascists built their support and policy on negative integration. This was coupled with an alliance and hostile takeover of the political right. If the fascists were on the right, then, their most obvious enemies would be on the left. With street brawls and political assassinations, the Socialists most assuredly were an opponent of fascism. Was socialism, then, the antifascist movement? While the political fighting occurred between left and right, the fascists opposed another large group as well: the liberal establishment. The fascists eventually took violent action against liberalism as well, in the form of World War Two. Thus, fascism was against these political groups, but were those political groups antifascist in nature or in action? The answer is quite simply yes, these groups were antifascist. The common element between the antifascist groups was that joining them and being active within them was a voluntary action; this is opp osed to life in fascist regimes, wherein people were forced to become fascist. In this sense, fascism was totalitarian, because it made everyone become part of the system or else wanted by the police. The freedom in the liberal system, wherein people were Catholic, democratic, socialist, communist, and so many other things, was in opposition to the very idea of that freedom being taken away. People willingly joined these groups, making an antifascist credo easier to define, because it was a choice to be antifascist. Certainly a more complex definition of fascism is required. However, the framers of fascist thought itself, Mussolini and Hitler, never truly bothered to define fascism for their supporters or for posterity. Mussolini tried in the Enciclopaedia Italiana of 1932, published a full 10 years after Mussolini took power. Mussolini said that his â€Å"own doctrine, even in this period, had always been a doctrine of action† (Mussolini, 586). This is the most obvious facet of fascism, its love of action; it is in the name of action that no true doctrine was ever laid out (Mussolini, 587). Mussolini proceeded from there to explain fascism in negative terms, saying: â€Å"For us fascists, the State is not merely a guardian†¦nor is it an organization with purely material aims†¦nor is it a purely political creation, divorced from all contact with the complex material reality which makes up the life of the individual and life of the people as a whole.

Obstacles Older Adults Nutritional Food Health And Social Care Essay

As concluded by a reappraisal of the literature, the subject of hungriness and older grownups is drastically understudied. However, hungriness is an issue impacting the older grownup Afro-american population peculiarly in hapless, developing metropoliss such as Chester, Pennsylvania. The intent of this survey is to look into the barriers to nutrient security among the aged life in this country and farther heighten the current research ; the focal point will be on deficiency of mobility, socioeconomic position, and deficiency of cognition on proper nutrition and where to entree equal nutrient. The information will be gathered by a subjective question/answer study entitled Household Food Insecurity Access Scale ( HFIAS ) . This study will be distributed to Afro-american grownups 65 and older life in the Chester, PA country. The informations acquired from this survey will ease the execution of future plans in order to give older grownups in the Chester, PA country equal entree to nutrit ionary nutrient. The troubles of turning old frequently make one think of an addition in furrows, trouble with mobility, finance problems, worsening wellness, and loss of sight. However, a common happening non thought of when discoursing the predicaments of an older individual is hunger stabs ; the aged often experience a deficiency of equal nutrition, trouble affording repasts, jobs with mobility impacting trips to a food market shop, and a figure of other factors impacting their entree to nutritionary nutrient. The combination of these factors make it highly hard for aged grownups, particularly those populating in ignored metropoliss like Chester, Pennsylvania, to achieve equal nutrient and nutrition in order to pull off a healthy life style. To do affairs more hard, the aged are frequently excessively proud to inquire for aid when it comes to any of the battles they face as a member of the older population, doing an inauspicious consequence on their wellness, wellbeing, and quality of life. The Current State of the Problem The continuity of hungriness in a development, hardworking state like the U.S. is â€Å" the most profound contradiction of our age † ( Cohen & A ; Reeves, 2005 ) . About 800 million in the underdeveloped universe, about 20 per centum of the entire population, are inveterate malnourished ( Cohen & A ; Reeves, 2005 ) . Research has besides shown that at least 2 billion people suffer from vitamin and mineral lacks ( Cohen & A ; Reeves, 2005 ) . The aged are a population enormously at hazard for this terrorization world. As the baby-boomer population is coming of age, there is a important rise in the Numberss of aged people in society ( Metz, 2000 ) . Research shows that people 65 and older represent 37 million people in the U.S. , about 12 per centum of the population at big. With such a representative per centum of Americans in this class, the troubles impacting their quality of life are of important importance. Quality of life in old age can frequently be affected by mobility, finance problems, unequal nutrition, sick wellness, and other troubles, although the relationship is non clear ( Metz, 2000 ) . Literature Review Discussions of the older population normally focuses on the disablements that diminish older grownups ‘ capableness to â€Å" obtain nutrient and and/or prepare repasts † ( Roe, 1990 ) . In a survey of hungriness and the aged, Schlenker ( 1984 ) â€Å" concluded that deficiency of entree to cooking installations may explicate their reported hungriness † ( Roe, 1990 ) . Poverty has besides been identified as a finding factor of diet insufficiencies in the aged ( Roe, 1990 ) . Posner ( 1979 ) â€Å" emphasized that those aged with really low incomes non merely hold less money to pass on nutrient, but they besides may hold more disablements that diminish nutrient entree than less destitute elderly, who have better wellness attention † ( Roe, 1990 ) . These factors have all been identified as critical determiners of hungriness and unequal entree to nutrient, yet no old surveies have determined which factors have a conjoining consequence, a more terrible impact, and how to repair these issues. The day of the months of these surveies, all before 1990 besides necessitate the demand for a more recent survey ; â€Å" Governments and international and national bureaus implementing nutrient and nutrition plans need information on the population ‘s nutrient insecurity to inform determination devising, proctor alteration and measure impact † ( FANTA, 2008 ) . The construct of mobility can hold an impact on many other countries of life, such as it does on adequate entree to nutrition. A research survey to achieve more information in this country is necessitated peculiarly because by look intoing the loss of mobility with increasing age and the impact this has on accessing equal nutrition could heighten the quality of life for an older individual ( Metz, 2000 ) . Adequate nutrition and wellbeing are of import facets of remaining healthy, yet can go progressively hard with old age ; by researching the barriers forestalling good wellness and nutrition in old age, such as mobility, societal workers and research workers will break measure the demands of the aged population and how to supply good services. Socioeconomic factors may besides foretell hungriness and subsequent ailment wellness ( Biros, Hoffman, & A ; Resch, 2008 ) . Surveies have shown and estimated household income to be a factor forestalling persons from accessing equal nutrition ( Olson, 1999 ) . It is to no surprise that those with a lower income experience hungriness at a higher degree ; this is due to the fact they can non afford proper nutritionary nutrient and settle for fast nutrient eating houses or frozen processed nutrient. The aged population is no different. As stated above, this has an highly negative consequence on their wellness, every bit good as their emotional and mental wellbeing. The emphasis that can ensue due to the concerns and concerns an person of hapless socioeconomic position faces are a hapless influence on their mental, emotional, and physical wellbeing ( Biros, Hoffman, & A ; Resch, 2008 ) . A combination of these factors, every bit good as the deficiency of equal nutrition, can hold a long permanent negative impact on the wellness of an aged individual. Although money is a major cause of nutrient insecurity, seniors sometimes â€Å" have adequate money for nutrient but are non able to entree nutrient because of transit or functional restrictions, or are non able to decently utilize nutrient because of functional damages and wellness jobs † ( Wolfe, Frongillo & A ; Valois, 2010 ) . Although frequently hungriness in the U.S. is linked to poverty as a status reflecting unequal resources, it can besides be linked to miss of cognition about said resources. In a survey by Carlson, Andrews, and Bickel ( 1999 ) , an estimated 11.9 % of U.S. families ( 35 million people ) were nutrient insecure. Among these, 4.1 % of families ( with 6.9 million grownups ) â€Å" showed a repeating form of hungriness due to unequal resources for one or more of their grownup aˆÂ ¦ sometime during the period † ( Carlson, Andrews, & A ; Bickel, 1999 ) . Many older grownups remain uninformed about the utile beginnings that can assist them discontinue their hungriness, and are hence uneducated about ways to achieve equal alimentary nutrient. Other effects of hapless nutritionary position include wellness, â€Å" in the broadest sense of [ the word ] including societal and mental wellbeing every bit good as physical wellness and overall quality of life † ( Olson, 1999, p. 521 ) . Hunger is associated with chronic hapless wellness and may coerce the aged to do picks that acutely impact their physical wellness and wellbeing ( Biros, Hoffman, & A ; Resch, 2008 ) . It is of import in societal work research to acknowledge how nutrient insecurity can impact wellness and overall quality of life either straight or indirectly through nutritionary position particularly in old age. The wellness effects of nutrient insecurity among the aged population comprise a potentially rich country for future, socially relevant research in the Fieldss of nutritionary scientific disciplines and geriatrics. The scaring hazard of hungriness can be associated with â€Å" compromised psychosocial operation † and other refering emotional provinces ( Olson, 1999 ) ; these are factors of immense concern for persons stand foring at least 12 per centum of our state ‘s population. This survey will find the prevalence of hungriness, the barriers forestalling this sensed hungriness, and its sensed wellness effects among the aged. As concluded by a reappraisal of the literature, and antecedently stated, the relationship between hungriness and older grownups is comparatively understudied. However, as illustrated, hunger is an issue impacting the older grownup population. Similarly, the aforesaid factors are issues blighting the lives of older grownups that can do it even more hard to stay healthy and eat alimentary nutrients. It is necessary to look into more on this subject by planing a survey to farther heighten the current research in this country in order to assist the older, hungry population. The intent of this survey is to place what obstructions, if any, are forestalling older Afro-american grownups in the Chester, PA country from accomplishing equal nutritionary nutrient. This peculiar survey will concentrate on deficiency of mobility, socioeconomic position, and the absence of cognition on nutritionary beginnings of nutrient. The research inquiries will be: Are there barriers forestalling older Africa n American grownups from accessing equal nutrition? Make these barriers include small to no mobility, finance problems, and deficiency of cognition? What can we as research workers to make arrest and prevent this job for the hereafter? With the informations collected from the study, plans will be implemented to ease the distribution of nutritionary nutrient within the country in an attempt to discontinue the bing job of hungriness in the older grownup population. In a similar attempt, participants will have a press release on where to travel to acquire nutrient, consciousness on proper nutrition, and how to manage their fundss in order to properly supply for their households appetites. The Demographics Although much of the research and information stated therefore far reflects the older population at a wide degree, the African American older grownups populating in Chester, Pennsylvania are no different, and may in fact experience all of these negative factors at a much higher degree. People 65 and older represent 11.8 per centum of the population in Chester, PA and 15.6 per centum of the Pennsylvania population at big harmonizing to the 2008 US Census ( US Census ) . Furthermore, the lives of these older grownups are made more hard as Chester, Pennsylvania is a instead developing and unfortunate, neglected community. The average family income in this country is $ 33,365, which is significantly less than the mean Pennsylvania household income of $ 50,713 ( City-Data, 2008 ) . Residents with income below the poorness degree in 2008 was at an dismaying 27.2 per centum while the remainder of the province is at a much more stable per centum of 11 per centum ( City-Data, 2008 ) . The pop ulation in Chester, PA has 16.7 per centum of persons unemployed, a per centum much above province norm ( City-Data, 2008 ) . Similarly, the African American population per centum is significantly higher than province norm at 74.6 per centum ( City-Data, 2008 ) . In footings of nutrient environment statistics, the metropolis does non hold a food market shop within its metropolis bounds coercing occupants to go forth Chester to make their nutrient shopping. Furthermore, Chester is # 84 on the list of â€Å" Top 100 least-safe metropoliss in the U.S. † ( City-Data, 2008 ) . The combination of these unwanted statistics paints a graphic image of the neglected community that is Chester, PA. As if older grownups do non hold adequate jobs impacting their entree to adequate nutrition, it is clear to see that the African American older grownup population in Chester, PA has significantly more factors blighting their wellness and nutrition. In a survey by Wolfe, Frongillo, and Valois ( 2010 ) , Afro-american seniors are one population in peculiar that suffers from nutrient insecurity. Many urban elder African Americans rely on borrowing money from friends, â€Å" purchasing nutrient on recognition from local grocers, trusting on aid from close friends or household who were non ever able to supply the aid needed or making without. † With the bulk of the Chester, PA population in this class, an outstanding 74.6 per centum ( City-Data, 2008 ) , the senior Afro-american grownups who suffer from hungriness in this country demand help achieving satiating, alimentary nutrient. It is clip to acknowledge that adult females and kids are non the lone persons enduring from hungriness and malnutrition ; seniors are besides a group of greatest concern ( Wellman, Weddle, Kranz, & A ; Brain, 1997 ) . The high degree of malnutrition among America ‘s older grownup is non merely unacceptable, but it is preventable ( Wellman et.al. , 1997 ) . It is necessary to increase public consciousness of the issue of hungriness and older grownups through this research survey in order to help older individuals in accessing equal nutrition. On a similar note, the fact that many of the surveies aforementioned in this literature reappraisal are dated by more than 5 old ages warrants a demand for this research survey. The intent of this survey is to look into the barriers to nutrient security among the aged life in this country and farther heighten the current research ; the focal point will be on deficiency of mobility, socioeconomic position, and deficiency of cognition on pro per nutrition and where to entree equal nutrient. RESEARCH QUESTION What are the possible obstructions forestalling older grownups in the Chester country from having equal nutrient and nutrition? MEDTHODOLOGY Sampling & A ; Recruitment Procedures The population in this research survey includes Afro-american older grownups age 65 and older residing in Chester, PA, non in a nursing place or other healthcare installation. The names of the persons will be acquired from the Delaware County Office of Services for the Aging ( COSA ) . The sample will include both males and females in parts reflecting the current population ‘s per centums since the sample is critical to external cogency ; the findings can so be generalized to the larger mark population. The choice procedure will be done indiscriminately ; the topics in the survey will be chosen at random from the population. Every 3rd individual ‘s name on the list of older Afro-american grownups in Delaware County from COSA will be selected to finish the study. The participants will finish a consent missive that assures they understand their namelessness and confidentiality will be ensured. Study Design This is an exploratory survey which will specify the obstructions forestalling older grownups in the Chester country from having equal nutrient and nutrition. The information will be obtained from a assorted method cross-sectional attack. The participants will first finish a self-report study, followed by a more prodding interview in order to derive more cognition on this subject. The study is the Household Food Insecurity Access Scale ( HFIAS ) for Measurement of Food Access is obtained from the United States Agency for International Development ( USAID ) . Measurement/Instrumentation For the intent of this survey, hungriness will be defined as holding â€Å" limited or unsure handiness of nutritionally equal and safe nutrients or limited or unsure ability to get acceptable nutrients in socially acceptable ways † ( Anderson, 1990, p. 1598 ) . Lack of mobility will include troubles traveling because of hapless articulations, arthritis, and other age-related troubles, every bit good as deficiency of a auto, or any other agencies of transit to the food market shop. Low fiscal position will be defined as the inability to decently supply alimentary nutrient, along with other necessities, for oneself and others in the place. The nutrient security study, Household Food Insecurity Access Scale ( HFIAS ) for Measurement of Food Access, will inquire each participant to self-report about their experiences and behaviours that indicate nutrient insecurity, â€Å" such as being unable, at times, to afford balanced repasts, cutting the size of repasts because of excessively small money for nutrient, or being hungry because of excessively small money for nutrient † ( Food and Nutrition Technical Assistance Project, FANTA, 2008 ) . The HFIAS â€Å" is based on the 18-question U.S. Household Food Security Survey Module ( US HFSSM ) , which asks respondents to depict behaviours and attitudes that relate to the â€Å" spheres † , of the nutrient insecurity experience † ( FANTA, 2008 ) . These spheres include: â€Å" 1 ) anxiousness and uncertainness about the family nutrient supple, 2 ) insufficient quality ( includes assortment and penchants of the type of nutrient ) , and 3 ) insufficient nutri ent consumption and its physical effects † ( FANTA, 2008 ) . The inquiries are designed to be added to a standard baseline and concluding rating study. The consequences from old surveies empirical analyses showed the bulk of the graduated tables to hold good internal cogency for their informations sets. Similarly, the â€Å" external proof consequences were consistent with our analysis outlooks, but as a following measure we recommend that farther research be carried out to prove the external cogency of the index against extra indexs of nutrient insecurity and expected results of nutrient insecurity. The cogency was tested by proving the â€Å" internal, cross-cultural and external cogency of the HFIAS utilizing empirical informations collected by authoritiess, international and national bureaus in a assortment of states and operational contexts † ( FANTA, 2008 ) . Data Collection Procedures The study will be sent out, with anterior warning via a telephone call, to the person ‘s house and if non completed within 30 yearss, will be followed up with another telephone call. The nutrient security position of the person will be assigned based on the figure of food-insecure conditions reported in each of the spheres included. A high mark of nutrient insecurity on this trial will justify an aid plan from the province or local authorities. Other informations will be collected by detecting lodging conditions when with the participant for the in the flesh interview station study. Restriction There are a few possible failings and restrictions of this survey. First, the step of a self-report study is merely every bit accurate as the participant allows it to be ; self-report steps make it easy to be unfaithful when replying inquiries on one ‘s wonts and behaviours and this fact needs to be taken into consideration when analysing the consequences of this survey. In a similar manner, the aged is a population plagued with memory loss. The participants in this survey may non remember the information questioned precisely as it happened or describe the information right because of memory loss. The aged population besides experiences feelings of shame and embarrassment when describing they can non supply for themselves making the same consequence as the following two issues-inaccurate coverage. Significance OF THE STUDY As stated in the literature reappraisal, much of the bing research is really much so out-of-date. In an attempt to spread out upon the research and concentrate more on smaller populations whose hungriness is a concern, this survey will concentrate chiefly on the Afro-american older grownup population of Chester, PA. The survey is important because, as stated before, â€Å" authoritiess and international and national bureaus implementing nutrient and nutrition plans need information on the population ‘s nutrient insecurity to inform determination devising, proctor alteration and measure impact † ( FANTA, 2008 ) . The deductions of these findings will help the older African American grownups in this country in achieving equal nutrition which will increase their quality of life and healthy wellbeing. The consequences of these findings will better the wellbeing of the current societal work patterns in this country by get downing groups, a societal service plan and other sign ifiers of societal work in general. Mentions Biros, M. H. , Hoffman, P. L. , & A ; Resch, K. ( 2008 ) . The Prevalence and Perceived Health Consequences of Hunger in Emergency Department Patient Populations. Official Journal of the Society for Academic Emergency Medicine, 12 ( 4 ) , 310-317. Carlson, S. J. , Andrews, M. S. , & A ; Bickel, G. W. ( 1999 ) . Measuring Food Insecurity and Hunger in the United States: Development. The Journal of Nutrition, 99, 510-516. Chester, Pennsylvania ( PA 19013, 19016 ) profile: population, maps, existent estate, norms, places, statistics, resettlement, travel, occupations, infirmaries, schools, offense, traveling, houses, sex wrongdoers, intelligence, sex wrongdoers. ( n.d. ) . Stats about all US metropoliss – existent estate, resettlement info, house monetary values, place value calculator, recent gross revenues, cost of life, offense, race, income, exposure, instruction, maps, conditions, houses, schools, vicinities, and more. Retrieved December 15, 2010, from hypertext transfer protocol: //www.city-data.com/city/Chester-Pennsylvania.html Cohen, M. J. , & A ; Reeves, D. ( 2005 ) . Causes of Hunger. International Food Policy Research Institute, 19, 1-5. FANTA Publications on New Approaches for Measuring Household Food Insecurity and Poverty: Adaptation of the US Household Food Security Scale to Developing Country Contexts 2004. ( n.d. ) . Welcome to FANTA-2 ( Food and Nutrition Technical Assistance II Project ) . Retrieved December 10, 2010, from hypertext transfer protocol: //www.fantaproject.org/publications/hfias.shtml Kendall, A. , Olson, C. , & A ; Frongillo, E. ( 1996 ) . Relationship of Hunger and Food Insecurity to Food Availability and Consumption. Journal of the American Dietetic Association, 96 ( 10 ) , 1019-1024. Metz, D. ( 2000 ) . Mobility of older people and their quality of life. Conveyance Policy, 7 ( 2 ) , 149-152. Olson, C. M. ( 1999 ) . Nutrition and Health Outcomes Associated with Food Insecurity. The Journal of Nutrition, 129 ( 2 ) , 521-524. Posner, B. M. ( 1979 ) . Nutrition and the aged. Lexington, MA: Lexington Books. Roe, D. A. , & A ; Schlenker, E. ( 1984 ) . Food Choices of the Elderly. Drugs and nutrition in the geriatric patient ( pp. 27-46 ) . New York: Churchill Livingstone. Roe, D. A. ( 1990 ) . In-Home Nutritional Assessment of Inner-City Elderly1- . Journal of Nutrition, 90, 1538-1543. Wellman, N. S. , Weddle, D. O. , Kranz, S. , & A ; Brain, C. T. ( 1997 ) . Elder insecurities: Poverty, hungriness, and malnutrition. American Dietetic Association. Journal of the American Dietetic Association ; , 97 ( 10 ) , 120-122.

Peace Building in West Pokot

Abstract Peace and stability are significant components of development in all spheres across the globe. These necessitated the emergence and growth of peace building and conflict management efforts world over. However, conflict related challenges continue to threaten the survival and continued existence of many groups, communities, states and regions in the world.In Kenya, an analysis of West Post Sub-county reveals the existence of multiple intervention efforts by the Government and several stakeholders In peace building and conflict management. However, little has been achieved so far as a result of these efforts. This study therefore examined peace building and conflict management programs In West Post Sub-county wealth the Republic of Kenya, and the residents' perceptions on the effectiveness of these programs In the Sub-county.Its Justification was based on an argument that West Post conflicts have had far reaching consequences to the residents of this study area and country at large. This study further focused on the Post-Turban conflicts and the subsequent peace building and conflict management initiatives in the area. Based on the outcome of this study, there were several peace building and conflict management programs in West Post Sub-county, many of which were carried out concurrently.Disarmament program was found to be unpopular with majority of respondents expressing disapproval due to its involvement of force and brutality, while the peace committee model was highly rated with most of the respondents approving it as largely inclusive. In conclusion, the Government should adopt a holistic approach that incorporates all approaches and stakeholders, especially the local communities. In addition, the Government should also address social issues that escalate conflicts.

Reviewing Prefix, Suffix, and Root Word Vocabulary

Reviewing Prefix, Suffix, and Root Word Vocabulary This exercise will give you practice in recognizing and using common prefixes, suffixes, and roots. Instructions For each sentence below, study the one word thats in bold print. See if you can identify the root word (or base) along with any prefixes and/or suffixes that are attached to it. After you have filled in all the blanks, compare your answers with those below. We watched a preview of the new Pixar movie.Root: ____________​Prefix: ____________The dancing cat was seen by more than two-million YouTube viewers.Root: ____________Suffix: ____________The teacher handed out paper hearts to the students who had done extra work.Root: ____________Suffix: ____________The magician made the rabbit disappear.Root: ____________Prefix: ____________At the end of his performance, the magician made a graceful bow to the audience.Root: ____________Suffix: ____________Shyla asked the magician for his autograph.Root: ____________Prefix: ____________Because of the lightness of the breeze, the sailboat moved quite slowly.Root: ____________Suffix: ____________Despite the heaviness of his backpack, Jack raced up the hill.Root: ____________Suffix: ____________Some dogs are shy or unfriendly, and they might bark or snap if you try to pet them.Root: ____________Prefix: ____________Suffix: ____________Esther quickly reopened the door and called for her cat.Root: ____________Prefix: ____________Suffix: ____________ We stood on a bluff overlooking the ocean.Root: ____________Prefix: ____________Suffix: ____________In todays world, no part of the globe is unreachable.Root: ____________Prefix: ____________Suffix: ____________My father never let anyone see him dressed informally.Root: ____________Prefix: ____________Suffix: ____________Everyone thought that Mr. Darcy was the proudest, most disagreeable man in the world.Root: ____________Prefix: ____________Suffix: ____________Preschoolers should have plenty of opportunities to run, play, and listen to stories.Root: ____________Prefix: ____________Suffix: ____________The speaker pointed out the unfairness of blaming high schools for the poor preparation of college freshmen in reading, writing, and math.Root: ____________Prefix: ____________Suffix: ____________ Answers Below are the answers to the exercise: Root:Â  viewPrefix:Â  pre-Root:Â  viewSuffix:Â  -ersRoot:Â  teachSuffix:Â  -erRoot:Â  appearPrefix:Â  dis-Root:Â  graceSuffix:Â  -fulRoot:Â  graphPrefix:Â  auto-Root:Â  lightSuffix:Â  -nessRoot:Â  heavySuffix:Â  -nessRoot:Â  friendPrefix:Â  un-Suffix:Â  -lyRoot:Â  openPrefix:Â  re-Suffix:Â  -edRoot:Â  lookPrefix:Â  over-Suffix:Â  -ingRoot:Â  reachPrefix:Â  un-Suffix:Â  -ableRoot:Â  formalPrefix:Â  in-Suffix:Â  -lyRoot:Â  agreePrefix:Â  dis-Suffix:Â  -ableRoot:Â  schoolPrefix:Â  -preSuffix:Â  -ersRoot:Â  fairPrefix:Â  un-Suffix:Â  -ness

Assess the View That Traditional Class Identities Are No Longer Important

These have the view that class no longer really matters in modern Britain and that now people no longer identify themselves according to their class background. Clarke and Saunders (1991) would agree with the view of postmodernists. They suggest that classes have become fragmented into many different groups and now they have been replaced with other influences such as gender and lifestyles. Although they is some evidence which suggests these ideas are exaggerated. Marshall’s survey into how people view themselves showed people still see social class as a source of identity. The traditional working class was a group of people that was developed after the industrialisation when they were need for large amounts of manual workers. This group formed a strong sense on culture and identity. These were strong moral values, having men as the breadwinner and women as housewives and believing getting a job is more important than having an education. The traditional working class also saw the labour party as the party for the working class as it represented their interests, as pointed out in item B. Although now many people in the working class vote for different parties as they don’t all agree on what is important now in society, supporting the idea that traditional class identities are no longer important. Now also the manufacturing business as changed a lot, this means now they aren’t the same jobs available as they would have been before as they have been replaced with things such as machines that can do a faster and cheaper job. Therefore the working class has had to change the sort of jobs they do over time which may be a reason for the change in characteristics, and therefore making the traditional class identities now no longer important. Diamond and Giddens agree with this as they argue that the working class is no longer important because of the change in the economy that as lead to the decline of manual labour jobs, and that the working class isn’t now the only class which experiences economic and social eprivation. The new working class is now seen to have little loyalty to others within the same class, more emphasis on customer goods, high levels of home ownership, and women likely to be employed. There is also now a larger section of the working class, this may be down to some working class jobs now becoming more skilful therefore getting higher pay, which others become less skilful and get lower pay, meaning people in the same class may identify themselves every differently. However there are sociologists that believe traditional class identities are still very important, for example Marxists. They believe social class is still hugely influential in shaping our identities. They also believe social class is identified by your income, and that leisure wouldn’t define your identity as you would need the disposable income to afford it. The British Attitudes Survey supported this idea, because in 2007 it found still 94% of people still identified themselves with a social class, whereas only 6% didn’t. Overall the importance of traditional class identities are seen every differently by different people. Views which agree and disagree to the importance of traditional class identities still being important have both positives and negatives so it’s hard to just believe one view point is the truth and the other doesn’t matter. Therefore I believe both viewpoints have sufficient evidence and that traditional class identities are still important to an extent, however now there is also other factors that can make up our identity other than just our social class.

Paul Brown Stadium Essay Example | Topics and Well Written Essays - 1000 words

Paul Brown Stadium - Essay Example The cost rose from $280 to an all inclusive costs of nearly $555 million (Albergotti & McWhirter). The county took out $1 billion in bonds to finance these projects. The county and its taxpayers are paying a hefty price for the bad decision that was made. In 2009 Hamilton County had to pay $34.9 million in costs related to the stadium deals which represent 16.4% of the county’s general fund. The normal cost to budget ratio in other counties that help finance stadiums is less than 2%. The county when the proposal was on the table exaggerated the economic benefits the new stadium would bring. Their absurd estimate was $300 million in benefits. These multi-million benefits never manifested. The stadium deal Hamilton County signed with the Bengals is considered the most lopsided deal in favor of a team in NFL history. It was a bad decision that will ruin the fiscal health of the county until the maturity date of the bonds. Currently 1 of 7 residents in Hamilton County is living be low the federal poverty line. 2) Who had ultimate responsibility for the problems? The person that is ultimately responsible for this debacle is the mayor of Hamilton County. He selected a team of three negotiators that acted as puppets of the Bengals. There was corruption and collusion in this deal evidenced by the fact that one of the negotiators, Bob Bedinghaus, joined the Bengals organization in 2001 as the team’s director of business development. The mayor should have never approved the project and he should have been the person negotiating the deal. He delegated a function that he is supposed to perform. Now the damage is done and the taxpayers of Hamilton County are paying a hefty price. That money that is being wasted paying for the expenses of billionaires could have been used to help a community that has 14.28% of its population living in poverty. Other political leaders in Hamilton County should have stepped in and spoke out against this move. Only a few political leaders spoke out against the deal. If the majority of the political leaders would have formed an alliance against issuing the bonds this whole fiscal mess would have never occurred. 3) Discuss the ethical implications of what occurred. This case study is an example of an ethical dilemma regarding governmental spending. The taxpayers are crying wolf now, but when the deal was signed thousands of fans were happy both teams stayed in Cincinnati. The Bengals deal was horrific. It does not make any sense why the county and its mayor approved such a lopsided deal. Hamilton County paid for the entire cost of building the new stadium, they have the Bengals a preferential lease agreement, they let the team keep all the parking revenues and the city is paying for all the securities costs. Hamilton County under any circumstance could not afford to pay for these stadiums themselves. They needed the help of other nearby counties, the city, and the state. They did not receive their support. It w ould have been better to let the Bengals go and keep the Reds in town. The Bengals deal was the deal breaker that destroyed the finances of Hamilton country for decades. 4) Are there any internal control issues to be addressed? A preliminary audit performed by PricewaterhouseCoopers found that there were insufficient financial controls by the project managers. The location move was a bad idea that increased the cost of the project by $70 billion. The contract could have had stipulation that mandated the stadium be

Summary Essay Example | Topics and Well Written Essays - 1000 words - 15

Summary - Essay Example She has termed the bigger dams a recipe of disaster that impacts the masses in a direct manner. She expresses her concern in the context of the price being paid by the ordinary citizen. The author of the â€Å"Greater Common Good† Arundhati Roy derives her repute and recognition from skills and pedigree in number of domains. Her notable works are â€Å"The God of Small Things (1997) ( Roy, 2002)†. Other notable works of Arundhati Roy include the â€Å"In Which Annie Gives it Those Ones† (Roy, ,2003) â€Å"Electronic Moon (1992)† along with the more talked about movie â€Å"The Great Indian Rape Trick† which was more significant on the account of tracing the life events of Polen Devi. Sardar Sarovar Dam being part of the Narmada Valley is an example of the same pattern where big dam is on the lines of development and construction and this in turn is bringing about all the challenges that are stated above. Arundhati Roy has taken up the case of Narmada River dams with regard to its facilitation, its terrain, impact on the people and other associated factors. The grey areas in case of dams’ construction come in form of the development line. The people do receive compensations and other packages but that is not like the actual case and feature. Little concern and consideration is given to the area of their rehabilitation in the context of mental disturbance and overall social stratification that takes place and hits back in a negative manner. According to Roy, the conventional mindset would for big dams based on the conventional stats and facts that they would serve as repository of water and other resources of natural life; however this would in actual stand as rhetoric only. The other side of the story and the page is given little regard and value. One of the common beliefs that is prevailing against the establishment of the reservoirs is that of the carbon dioxide repository and emission from these sources which further leads to imbalance in the

The importance brunttland report conncetion with tourism and travel Research Paper

The importance brunttland report conncetion with tourism and travel agency - Research Paper Example The report on the world tourism analysis of 2007 shows the number of international travelers had to increase enormously from 25 million in 1950 to 800 million currently. Brundtland report provides some analysis and recommendations for the sustainability of developments within the societies. This paper, therefore, will be highlighting the importance of the Brundtland report in connection with the tourism and travel agency (McChesney 43). Several governments have had to meet and approve Agenda 21 and the Rio declaration. The agenda 21 had to offer some blueprint on the sustainable development, while, on the other hand, the Rio Declaration had to articulate the vital principles for the sustainable development in the 21st century. The two documents enable the governments, organizations, and industries to work towards attaining the highest levels of sustainability as the Brundtland report defines that the development meeting the needs of the present without conciliating the ability of the coming generations to meet their own needs. However, the challenge is finding the balance between the sustenance, prosperity, and the people’s desire to be stable in financial, material well being with the underlying need for community, identity, home, and religion. Tourism and travel agencies, hence, plays a significant role in bringing some balance in these forces. Tourism and travel provides the livelihoods for the urban and the rural communities. It also enhance the community relations and make up the bridges of understanding and peace between countries, in which case it is possible when there is proper planning development and management (Sigala et. al. 43). The Brundtland Report considers the tourism and travel sector as the largest in contribution of the economy in the whole world. The report reiterates the main qualitative trends that one observes in the industry through the forms of increased market segmentation, development of new forms of tourism and the influenci ng of traditional package tours. Therefore, tourism and travel sectors have had to increase the market demand in various ways, in which case it has had to contribute the social, environmental and the economic sustainability. This has been possible by proper planning and management of the pressures from growth. The preservation of the tourism product, hence, helps in securing the future for many people. Many companies have had even to create stable responsible behavior. This is by ensuring they use their product and services to educate and inform their customers. This is in response to the need to safeguarding the natural resources (Sharpley 15). Tourism and travel, if utilized effectively, will go along the way in bringing a growth and economic success in the countries, both developing and developed. There is the potential that the markets enhance lives in a sustainable structure via providing the wealth creation, innovation, competition, and choice among others. The tourism and tra vel sector have these and other elements, in which case it enables it to be a vibrant market force for the future sustainability. The sector has the probability to increase exports, boost the economies GDP, bring in capital investment, and create employments. Tourism and travel creates jobs throughout the economy, both in organizations that get to involve directly in business and in the associated supplier industries,

Multifunctional Porous Organics Synthesis

Multifunctional Porous Organics Synthesis TITLE OF WORK The synthesis and characterisation of functionalized porous organics Abstract Lophine based radicals have been studied for many years due to their photochromic nature, recent literature has seen attempts to connect two radicals to carbon based backbones. In this report we will discuss attaching six lophine molecules to a single backbone which is a phosphazene ring. Cyclophosphazene rings have a unique conformation allowing for supramolecular architectures to be formed by varying the substituents, these architectures range from 0-2D structures. The hexalophine molecule exhibits 1D channels due its unique conformation which leads to the formation of a porous material. Porous organics are of high interest in recent literature due to them being a cheaper, less toxic alternative to MOFs as well as having the ability to be modified and tailored easily due to the simple starting materials. In this report we shall state synthetic pathways from simple molecular building blocks to hexalophine (32%) and two derivatives, compound 4 (46%) and 5 (15%). These two derivatives have the potential to increase pore stability. This report will also include the oxidation of hexalophine to its radical species which were found to display photochromic properties and it is also believed that this material could contain light gated pores which are closed in the dimer form of the product but then open upon irradiation of UV of 365nm. 1. INTRODUCTION 1.0 Properties and potential uses of Lophine This report will feature chemistry based upon the triphenylimidazolyl based radicals (TPIRs) as well as the dimer form hexaarylbiimidazole (HABI). Lophine (2,4,5-triphenyl-1H-imidazole) is a heterocyclic imidazole derivative where three phenyl rings are attached to the imidazole ring (figure 1), these imidazole derivatives are an area of importance due to the many interesting properties it possesses. Lophine has been of interest to researchers for many years with its chemiluminescent properties being first discovered in 1877 by Radziszewski.1 The oxidation of the lophine molecule follows the reaction scheme below, where lophine is oxidised to the TPIR radical state via addion of base and treatment with Fe forming one of six dimers both in solution and the solid state (figure 2). These materials display photochromic, thermochromic and piezochromic properties. The mechanism of photochromism of the lophine dimer is the homolytic cleavage of the 2C-1N bond of the dimer by irradiation wit h light, forming two lophine radicals.2 The fast colour change associated with this dimer opening means there is a potential use in display screens or as the basis for molecular switches, where irradiation with light opens the dimer forming the radical in turn switching the external component On/Off. These possible applications have caused a focus on creating methods to manipulate and control the colour of these materials and as well as to increase the rate of switching.3 The colour of the radical form is dependent upon the substituents on the ring, the more conjugated the system the further toward the red side of the spectrum the colour.4 Lophine displays piezochromic properties in its solid state, upon applying pressure lophine crystals the colour change of yellow to blue/green has been observed, this occurs via the radical dissociation of the 1N-1N dimer bond.5 Other more unusual modes have been of dimerization such as the 2C-2C have now also been isolated, this mode features a u nusually long C-C bond.3 Figure 1 The structure of Lophine (2,4,5-triphenyl-1H-imidazole) Another interesting lophyl radical derivative is the 1,8-TPID-naphthalene radical which consists of 2 lophine radicals connected by a naphthalene ring. 1,8-TPID-naphthalene has been characterised in the solid state by Abe et al; who studied the photoreactivity of the compound. 1,8-TPID-naphthalene allowed the group to fix two radicals onto a backbone meaning that the radicals were in close proximity and could dimerise easily as opposed to two radicals not connected via a backbone which first need to find eachother in order for dimerization to occur (figure 3). They found that the dimer could be cleaved photochemically giving the diradical and then could be thermally converted back to the dimer.6 They also found that the formation of a peroxide bridge was much more common than previous literature had accounted for. This bridging occurred when the 1,8-TPID-naphthalene radical was placed under an O2 atmosphere.7 This peroxide bridge formation is very important as when oxygen quenches th e spin to form the closed shell peroxide it does so irreversibly meaning the material is no longer photochromic. It was then shown that this peroxide degradation pathway can be generalised for the chromic dimers of TPIR materials, with non-tethered TPIRs forming similar peroxide bridges.8 A recent development by the same research group has also shown how a thiophene substituted phenoxyl-imidazole radical complex (PIC) can generate two non-equivalent radical upon irradiation with UV light. The colour change can be fine-tuned from tens of seconds to nanoseconds, however a sensitivity to lower wavelengths of light meant that applications were limited. This problem was rectified by adding a phenyl group to the 5 position of the thiophene ring.9 Figure 2 The six potential dimerization modes of two lophyl radicals.3 Figure 3 Illustrates the reversible conversion of 1,8-TPID-naphthalene between its radical and dimer forms. 1.1 Hexa-substituted Phophazene Rings, Tectons and Crystal Engineering A key component of this project was the exploitation of the Phosphazene ring as soft tecton; a tecton is a molecular building block that interacts with sticky sites, formally known as supramolecular synthons, via spatial arrangements to induce the formation of supramolecular aggregates. The search for new tectons is a hot area of research due to the constantly growing field of crystal engineering where the aim is to produce functional single crystal materials using intermolecular interactions. The arrangement of molecules in solid state structures is largely dependent on striking a fine balance between intramolecular forces and packing interactions, knowledge of these forces is key to the field of crystal engineering.10 In general, hard tectons interact via more robust synthons than soft tectons and therefore usually crystallise with unambiguous geometries. Whereas soft tectons and less robust synthons allow for the formation of supramolecular isomers (figure 4).11 These tectons allo w for many functional materials to be formed in a one pot synthesis, they also have the ability to be carefully adjusted to alter and improve upon their functionality.12 Cyclophosphazenes are extremely soft tectons that interact with soft synthons to give a large variety of supramolecular architectures in the solid state. The conformation of the cyclophosphazenes is also very interesting as three substituents reside above the plane of the ring and three below (figure 5). It was found that small modifications to the substituents attached to the ring gave supramolecular architectures ranging from 0D to 2D structures (figure 6) such as include monomer, dimer, cyclic hexamer, zigzag chain, linear chain, double chain, graphite-type sheet, rectangular grid and hexagonal close-packed sheet. Such variety of structures came from the easy rotation about the exocyclic P-N bonds, which allowed variable directionalities for all of the N-H bonds. 11   Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚   3a)  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚   3b) Figure 4a) Shows benzene-1,4-dicarboxylic acid a classic example of a hard tecton. 4b) shows a silanetriol a classic soft tecton. Figure 5 Conformation of a Hexa-substituted Phosphazene Ring. Figure 6 Schematic representations of aggregation patterns of (RNH)6P3N3 in the solid state.11 1.2 Magnetism and Magnetic Frustration The materials we aim to make during this project once appropriately oxidised should go on to form dimers which when irradiated with UV light form discrete radicals containing unpaired electrons thus giving each radical an associated magnetic moment. Neutral organic radicals tend to be paramagnetic and exhibit Curie- Weiss behaviour, where the spin vectors of the unpaired electrons are randomly aligned above the Curie temperature (Tc), which is the critical temperature below which the long ordered state is established, unless a magnetic field is applied. If spin vectors are parallel to each other below the Curie temperature then the material is ferromagnetic, if the spin vectors are aligned antiparallel to one another the material is antiferromagnetic.13 Due to the geometry of the phosphazene ring (three substituents pointing up above the plane of the ring and three below) there is the possibility of forming a 2D triangular lattice of spins if the substituents are organic radicals.   This could possibly lead to geometric magnetic frustration due to the fact that the two nearest neighbours to a spin are themselves nearest neighbours and therefore antiferromagnetic couplings cannot be satisfied (figure 7).14 This can lead to very interesting magnetic properties. Most solid state examples of this geometric frustration tend to be transition metal oxides, however, studies have been done on organic systems that also distribute geometric frustration.13 One example of this is m-MPYNNP+ which is a spin  ½ organic radical that upon dimerization forms a 2D triangular lattice which demonstrates the aforementioned geometric frustration.14 The issue of spin frustration has been around for a long time as Quantum spin liquids (QSL) were first theoretically proposed by Anderson many years ago which are now a hot topic of research due to the realisation of these QSLs in organic materials such as k-(ET)2-CH2(CN)3, which has a near perfect triangular lattice with angles very close to 120 °.15 A QSL is an exotic ground state where interacting spins continuously fluctuate with no formation of   low range magnetic order even at sufficiently low temperatures.16 Figure 7 Antiferromagnetic coupling cannot be fulfilled causing geometric magnetic frustration. 1.3 Porous Materials Porous materials are as important as ever due to their wide spread use in several fields such as catalysis and gas absorption,17 meaning they can play a critical role in the route to solving our growing energy shortage problems. Porous materials are instantly associated with materials such as zeolites, metal organic framework (MOF) and organic polymers. MOFs are characterised by their tuneable pores and inherent flexibility which more classical carbon or oxide based structures do not possess, this gives a wide range of applications for MOFs such as gas storage, separation, drug delivery or catalysis.18 Porous organics have been discovered in nature but are largely created synthetically and approaches often need to be coupled with knowledge of crystal engineering. These materials are often held together by directional forces which form extended frameworks of noncovalent interactions such as Ï€- Ï€ interactions, hydrogen bonding or coordinate bonding (figure 8).17 Like zeolites a nd MOFs porous organics have the ability to selectively absorb atoms and molecules in the gas phase.19 There are many positives to these porous organics, they are often cheaper to synthesise and less toxic as well as being far less dense than metal containing MOFs. Figure 8 One example of a Porous Organic by Sozzani et al. 1.4 P3N3 Hexalophine The chemistry of P3N3 Hexalophine incorporates much of the chemistry discussed above and has many interesting properties. The P3N3 Hexalophine molecule consists of six lophine substituents attached to the phosphazene ring via a P-O bond (figure 9). Previous work in the Robertson group found that the solid state structure of Hexalophine consisted of a pseudo hexagonal motif giving rise to 1D channels that run parallel to the stacking axis (figure 10). The molecule maintained its D3 symmetry in the solid state. The phenyl rings twist to maximise pi-stacking interaction and the 3 imidazole nitrogen atoms form hydrogen bonds to a central water molecule. There are 4 pi-pi interactions that stabilise this structure, the molecules are in a slipped conformation allowing the phenyl and imidazole to rings overlap. Other non-covalent interactions such as van der Waals interactions also help to stabilise the structure. The high symmetry of the structure which comes from the hexa substituted phos phazene ring (three above the plane of the ring and three below) gives an equal distribution of intermolecular forces giving a high probability of forming a stable porous structure. IGA measurements with CO2 loading at 195K shows a Type I isotherm with absorption reaching 8cm3g-1 at a pressure of 700mmHg confirming the materials microporosity. However only a small fraction of the void space contained CO2. Figure 9 The structure of Hexalophine. Figure 10 The crystal structure of Hexalophine, illustrating the 1D channels. 1.5 Aim of Project The aim of this project is to combine our knowledge of the chemistry of both lophine radical systems and cyclophosphazene rings to find elegant synthetic routes which will improve upon the porous properties of hexalophine. This will be done by varying the ring substituents to increase stability of the pores and to improve its gas absorption properties. Three lophine derivatives have been identified as plausible candidates for thid are where two of the phenyl groups on the lophine will be replaced by two thiophene rings and two pyridine rings respectively, with the position of the nitrogen in the pyridine ring being varied depending upon the synthetic pathway (figure 11). We wish to synthesise and fully characterise these derivatives including growing single crystals for structural studies via X-ray crystallography. Also a stoichiometric controlled oxidation of the hexalophine material to its neutral radical/dimer pair is required in order to further investigate the properties of hexa lophine such as the possibility of creating a photochromic material that has light gated pores that open on irradiation with UV light. R=  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚   or  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚   or Figure 11 the synthetic targets of this project. 2. Results and discussion 2.0 Hexa-benzaldehyde Synthesis The first step in this synthetic project involved attaching six benzaldehyde units to the phosphazene ring via a P-O oxygen bond. This was achieved by reacting the phosphonitrillic chloride trimer along with 6 equivalents of 4-hydroxybenzaldehyde, potassium carbonate in dry THF (figure 12). The reaction was monitored with 31P NMR which showed completion when only a singlet was present in the spectra indicating full substitution. This produced the compound 1 which was the precursor for many of the subsequent reactions. The reaction gave the desired product in a fairly low yield (45%). Whilst the yield was slightly low the FT-IR showed all of the characteristic absorptions such as C=O (1697cm-1) and CAr-CAr (1585cm-1). 31P NMR was conducted and showed a sharp singlet at 7.08ppm which indicated full substitution on the phosphazene ring as all of the environments are equivalent. 1H NMR was also conducted and show a singlet at 9.87ppm with an integration of 6Hs which was as expected for t he 6 aldehyde protons, two doublets were found in the aromatic region and integrated to 12Hs each which was correct for the number of protons expected. The CHN analysis was almost perfect with less than 0.2% difference from the calculated values, this indicated that the product was of high purity. Mass spectometry also indicated that the desired product had been synthesized as a [M+Na]+ peak was detected at 884. Figure 12 The reaction scheme for the synthesis of 1. 2.1 Synthesis of Hexalophine and Hexalophine derivatives 2.1.0 Using Diketones The synthesis of hexalophine and hexalophine derivatives is important due to their porous properties which can be of great importance in fields such as gas storage and catalysis. The method for attaching six lophine units to the ring was a ring condensation of 1 on the six benzaldehyde units attached to the phosphazene ring using a synthesis based upon Radziszewskis synthesis.1 The product 2 was achieved by reacting 1 along with six equivalents of benzil, ammonium acetate in excess in glacial acetic acid (figure 13). The yield for 2 was quite poor (32%), the FT-IR showed all of the characteristic peaks such as CAr-H (3055cm-1), C=N (1604cm-1) and CAr=CAr (1538cm-1) indicating the desired product had been formed. This was further confirmed by both the 31P and 1H NMR, the 31P NMR showed a singlet at 8.36ppm which indicates full substitution on the phosphazene ring. The 1H NMR showed a singlet at 12.65ppm which had an integration equal to 6Hs which is representative of the 6 imidazole N -Hs, it also showed multiplets in the aromatic region with an integration of 84Hs which is exactly the number of aromatic hydrogens in the desired product. CHN analysis of the product correlated well with the desired structure, especially when three molecules of water were factored into the calculation. It is unsurprising that this compound also contained water due to its porous nature.   Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚   NH4OAc   Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚   Acetic acid (6eq.) Figure 13 The reaction scheme for the synthesis of 2. Another reaction designed based upon the ring condensation reaction was the synthesis of 4. This synthesis builds upon the diketone functionality as above, however, in this reaction the R groups of the diketone thenil were thiophene rings as opposed to the phenyl rings of benzil. Thenil like benzil was reacted with 1 and ammonium acetate in glacial acetic acid (figure 14). The yield for this compound, whilst better than 2, was still fairly low (46%). FT-IR showed the characteristic peaks such as CAr-H (3071cm-1), CAr=CAr (1643cm-1) and C=N (1607cm-1) indicating the target molecule had been synthesised. The 31P NMR showed a singlet at 8.26ppm again indicating full substitution. The 1H NMR showed a singlet 12.91ppm with an integration of 6Hs representative of the 6 imidazole N-H hydrogens, it also showed multiplets in the aromatic region with an integration of 60 which was again exactly what was required for the number of aromatic hydrogens, indicating the correct product had been synt hesised. The CHN analysis was close to the theorectical values required especially when four water molecules were factored in, again this is unsurprising as this material like 2 is also expected to be porous.   Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚   NH4OAc   Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚   Acetic acid (6eq.) Figure 14 The reaction scheme for the synthesis of 4. Like thenil and benzil, pyridil is also a diketone where the two R groups are heterocycles, in this case the two heterocycles are pyridine rings. Pyridil was used again with the classical Radziszewski based synthesis to synthesise the compound 5 (Figure 15). The yield for this compound was very low (15%) due to a lot of mass lost upon recrystallization and decomposition upon heating. The FT-IR showed the correct absorptions for the key functional groups such as C=N (1600cm-1) and P=N (1158cm-1) indicating that the target compound had been synthesised. However large OH absorption band (3349cm-1) was also present showing that the product contained a considerable amount of water or ethanol. CHN analysis of the compound showed a vast difference in carbon and nitrogen values when compared to the theoretical values indicating some impurities in the sample. The fact that the product contained considerable amounts solvent would also skew the result of the CHN analysis somewhat.   Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚   NH4OAc   Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚   Acetic acid (6eq.) Figure 15 The reaction scheme for the synthesis of 5. 2.1.1 Using Aldehydes for an alternative preparation The idea of using aldehydes such as pyridine carboxyaldehyde and benzaldehyde as opposed to the diketones used above was born when questioning on how we could stabilise the pores in the materials we wished to synthesise as larger groups could be added to these aldehyde starting materials. An alternative synthesis of 2 using twelve equivalents of benzaldehyde is illustrated in figure 16. The reaction was left to reflux for 7 days however the 31P NMR showed a multiplet indicating that full substitution had not occurred or a mix of products was present. Unfortunately, this was a reoccurring theme as the failed synthesis of 3 using twelve equivalents of pyridine carboxyaldehyde (figure 17) also showed a multiplet in the 31P NMR. Benzaldehyde (12 eq.) Figure 16 The reaction scheme for and alternative preparation of 2. Carboxyaldehyde (12 eq.) Figure 17 The reaction scheme for compound 3. 2.2 Oxidation of Hexalophine and its derivatives The oxidation of hexalophine is of great interest due to the potential properties it may possess, such as it possessing photochromic properties which may lead to light gated pores. For this oxidation an excess of potassium hydroxide was used to create the anion before 50 equivalents of the classical oxidising agent potassium ferrocyanide (III) were used to perform a one electron oxidation to the radical species 6, a yellow to orange colour change is associated with the formation of the radical species. This radical species quickly dimerises and an orange to yellow colour change is associated with this. Upon irradiation with UV light (365nm) the dimer opens to form two radicals, the colour change associated with this was yellow to purple displaying the photochromic behaviour of this compound (figure 18). The radical species is stable for a number of hours in the solid state unless gentle heating is applied which induces dimerization again and the colour change of purple to yellow is a ssociated with this. FT-IR showed characteristic absorbances of CAr-H (2955cm-1), C-N (1301cm-1) and P=N (1198cm-1) which are present in the desired product. The thiophene hexalophine derivative 4 was also oxidised using the same classical oxidation conditions as above to form its radical species 7. Upon separation the system formed 3 layers, an organic layer, an aqueous layer and a solid substance formed which was soluble in neither. Both the organic layer and solid substance were irradiated with UV light to test for photochromic properties however neither displayed a colour change and thus further testing of this material via UV/Vis spectroscopy is required to determine its nature. Figure 18 A RBF containing the hexalophine dimer and radical, the purple is the radical species, the yellow is the dimer species. 3. Conclusions and further work The aim of this project was to synthesise and characterise functionalised porous organics based upon hexalophine as well as to perform oxidations to the radical species and study their properties such as photochromism. For the most part the aim of the project has been met as two derivatives of hexalophine (4 and 5) and hexalophine (2) itself have been synthesised from simple molecular building blocks and characterised using a range of spectroscopic techniques such as NMR, FT-IR and CHN analysis. The next step in the characterisation of these materials would be to gain crystal structures via x-ray crystallography to show the packing arrangement of these molecules and to prove the existence of pores with in the molecule created from the unique conformation of the phosphazene ring. Additionally, once crystal structures have been gained gas absorption test should be taken to test both the gas uptake properties and selectivity of certain gases. Yields for these experiments were quite low and the aldehyde reactions did not demonstrate full substitution onto the ring, one possible solution would be to try the reaction in a Parr pressure reactor. The oxidation of hexalophine was carried out with great success as the experiment demonstrated the proposed photochromic nature of the material, also the stability of this material with respect to air was very surprising. If possible crystal structures for this material should be obtained in order to investigate further the possibility of light gated pores which when the molecule is in the dimer form are closed but once in the radical form are open. 4. Experimental details 4.0 Ma